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I have cleaned files, Stanley planes and plane irons, and Maytag Model 72 engine parts. A guy at our hunting camp asked me to clean a gun barrel that was rusty and when I do, I plan to run a piece of stainless steel wire rope down the bore. The wire will be separated from the barrel by short pieces of plastic tubing.One note about electro cleaning - it can cause hydrogen embrittlement which weakens the metal so the gun will no longer be shootable.
That's what my wife says. I have subjected her to many out-of-the-blue engineering calculations over the years when we've been driving somewhere or sitting in a restaurant. Every time we go to a restaurant that has one of those little trains running around she reminds me of the annual mileage estimation I did about 8 years ago at a lunch counter in Boone, NC. When you think about those trains, you realize that they really racking up the miles!Back to the subject at hand. After doing some Googling and reading on the subject, here is a summary:1. Hydrogen embrittlement (HE) can occur when tiny hydrogen bubbles (one web page called them blisters) become incorporated in internal delaminations or non-metallic inclusions of a metal.2. Several processes can get hydrogen at the surface of the metal, including plating, cathodic cleaning, and the metal being located in a high temperature or pressure environment where hydrogen gas is present. We fall into the cathodic cleaning group.3. Some metals, such as high strength and alloy steels are more susceptible to HE, but it can happen to cast iron.4. The tiny bubble causes stress concentration points. These can lead to rapid failure, especially in parts that are subject to tensile stress.5. Parts are baked to drive out the hydrogen and reduce the likelihood of a HE-induced failure.I don’t think HE is a concern for a cathodically-cleaned skillet that has been seasoned because of the multiple heating cycles. Besides, the flakes of graphite that are present in grey iron create many stress concentration points and hydrogen probably isn’t going to make a skillet more brittle than it is already.